G lime-water, when it is coloured or dyed orange. In each little tubular cotton fibre the same change goes on as went on in the glass vessel, and as the tube or glass vessel looks orange, so does the fabric, because the cotton fibres or tubes are filled with the orange chromium compound. You see this is quite a different process of pigment colouring from that of rubbing or working a colour mechanically on to the fibre. Let us now turn to the substantive colours (Group I.), and see if we can further sub-divide this large group for the sake of convenience. We can divide the group into two--(_a_) such colours as exist ready formed in nature, and chiefly occur in plants, of which the following are the most important: indigo, archil or orchil, safflower, turmeric, and annatto; (_b_) the very large sub-group of the artificial or coal-tar colours. We will briefly consider now the dyestuffs mentioned in Group (_a_). _Natural Substantive Colours._--Indigo, one of the most valuable dyes, is the product of a large number of plants, the most important being different species of _indigofera_, which belong to the pea
family. None of the plants (of
which _indigofera tinctoria_ is the chief) contain the colouring matter in the free state, ready-made, so to say, but only as a peculiar colourless compound called _indican_, first discovered by Edward Schunck. When this body is treated with dilute mineral acids it splits up into Indigo Blue and a kind of sugar. But so easily is this change brought about that if the leaf of the plant be only
bruised, the decomposition ensues, and a blue mark is produced through separation of the Indigo Blue. The possibility of dyeing with Indigo so readily and easily is due to the fact that Indigo Blue absorbs hydrogen from bodies that will yield it, and becomes, as we say, reduced to a body without colour, called Indigo White, a body richer in hydrogen than Indigo Blue, and a body that is soluble. If this white body (Indigo White) be exposed
to the
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